Water is the chemical to which fabricated products are exposed most frequently. Water and high temperatures such as those used during processing can cause hydrolytic degradation by attacking the carbonate linkages, breaking the polycarbonate polymer chain, and lowering impact and tensile strength.

  As with most chemical reactions, the rate of attack depends on time and temperature. At standard room temperatures, there is no noticeable loss of properties after many years of contact with water. Contact with water at 140¡ÆF (60¡ÆC) and intermittent contact at temperatures up to 212¡ÆF (100¡ÆC) may have little effect on properties. Severe conditions, such as those in steam autoclaves, however, may alter the clarity and toughness of the polymer faster. Therefore, the use of polycarbonate in such applications is limited and dependent on the autoclave cycle time and temperature.

  Because the primary effect of hydrolysis is reduction of molecular weight, selection of a low melt flow rate (high molecular weight) CALIBRE* polycarbonate resin will assure the greatest possible retention of resin properties. This is why proper drying of polycarbonate resins is critical in obtaining the best performance from the polymer. For specific information on drying, refer to the "Processing Guidelines" section.

Chemical Resistance Ratings of CALIBRE Polycarbonate Resins at 73¢µ(23¡É),50% RH
General
Reagents
Acids,
dilute
Acids,
concentrated
Alkalis Organic
solvents

Alcohols
 
Organic
solvents

Chlorinated
hydrocarbons
Organic
solvents

Aromatic
hydrocarbons
Organic solvents
Aliphatic
hydrocarbons
Cooking
oils
Resistance
Rating
Good Fair-Good Poor-Fair Good Poor Poor Poor-Fair Good

General
Reagents
Lubricating
oils
photo-
chemicals
Detergents Ester Ketones Phenols Salts
Acidic
Salts
Basic
Salts
Neutral
Resistance
Rating
Good Good Good Poor Poor Good Good Fair Fair

Specific
Reagents
Zinc
Stearate
Ethylene
glycol
Methanol,
ethanol
Acetone Motor oil Gasoline Brake fluid Methylene
chloride
Trichloroethane
Resistance
Rating
Poor Good Good Poor Good Fair Poor Poor Poor

  The information provided in the previous table is a brief general guide to the chemical resistance of CALIBRE resins. Testing was conducted using ASTM D 543 and other similar methods in which product specimens with low internal stresses are weighed and tested for tensile strength, then immersed in the reagent for a period of 180 days. Upon removal, any change in weight and/or tensile strength are recorded, with resistance ratings defined as follow:

Good - Little or no reduction in physical properties; change in weight under 1 percent and change in tensile strength under 5 percent.

Fair - Some reduction in physical properties occurs after long exposure, with either a change in weight of more than 1 percent or a change in tensile strength of more than 5 percent.

Poor - Significant changes in physical properties after short exposure to the substance, with both a change in weight of more than 1 percent and a change in tensile strength of more than 5 percent. Use of CALIBRE polycarbonate resins is not recommended in these applications.

NOTE : Ratings listed are only indications and should not be interpreted as absolute proof of resistance of any part against a certain reagent. Testing of the actual parts under actual conditions of exposure is recommended to provide a more accurate indication of performance.



"*" Trademark of the Dow Chemical Company, licensed for use by LG DOW Polycarbonate LTD.